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Self-Ignition of Deep-Sea Sulfide Minerals Poses Fire Hazards During Extraction

Потенційні ризики займання при видобутку сульфідних мінералів з глибоководних районів. Photo: НВ — Техно

An Unexpected Danger Beneath the Waves

Minerals extracted from the ocean's depths can spontaneously catch fire when brought to the surface. Scientists at the U.S. Geological Survey (USGS) have identified that deep-sea sulfide minerals are prone to self-ignition during ascent, presenting a significant fire risk in underwater mining operations, particularly in the Escanaba Trough.

This phenomenon is primarily driven by nanocrystalline marcasite, a form of iron sulfide that becomes unstable in the presence of oxygen. The research was conducted in collaboration with the Bureau of Ocean Energy Management (BOEM) and the National Oceanic and Atmospheric Administration (NOAA).

Hazards of Deep-Sea Mining

In 2022, metal sulfide rock samples were collected from great depths in the Escanaba Trough. Laboratory tests revealed that exothermic reactions within these samples caused temperatures to exceed 100°C, leading to complete oxidation and destruction of the material. Marcasite was identified as the main agent triggering this explosive self-heating by reacting violently with oxygen.

While these minerals remain stable under the high-pressure, low-temperature, and oxygen-free conditions found deep underwater, exposure to surface environments during transport to ships or land drastically increases the risk of fires aboard mining vessels and barges. The findings were published in the journal Scientific Reports, aiming to alert industry stakeholders and the public to these potential dangers.

Moreover, as deep-sea mining expands, it threatens fragile ocean ecosystems. This study highlights the urgent need for cautious development of extraction technologies and careful assessment of their environmental impact.

Understanding the self-ignition behavior of sulfide minerals is crucial for the mining sector to prevent serious accidents and ecological damage. The research underscores the importance of ongoing investigation and stringent control of deep-sea mining methods to ensure safer practices and minimize environmental harm in future operations.

As the risks associated with deep-sea mining become increasingly apparent, it is essential to consider other environmental threats posed by human activities in oceanic depths. Recently, a troubling discovery revealed over 3,300 containers of radioactive waste on the Atlantic Ocean floor, highlighting the urgent need for comprehensive regulations to protect fragile marine ecosystems from various hazards.